Sky then announced that she would be using her contract to face the new Knockouts Champion Angelina Love in a Leather and Lace match the following week.
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At Hard Justice, Sky, along with Love, competed in a tag match against ODB and Cody Deaner in a losing effort when Deaner pinned Sky, resulting in Love losing the Knockouts Championship to ODB.
The last of the four quarter final matches pitted The Beautiful People against Rayne and a mystery partner, who was later revealed to be the returning Roxxi.
When Sky tried to make the save, she was attacked by the returning ODB and Jacqueline, who were then in turn attacked by the also returning Traci Brooks.
On October 16 at Bound for Glory, Sky won the Knockouts Championship for the first time by defeating previous champion Winter, Madison Rayne and Mickie James in a four-way match, when Traci Brooks replaced original special guest referee Karen Jarrett, and counted the deciding pinfall.
She won her first championship in professional wrestling, the WXW Women's Championship, after winning a battle royal on May 29, 2004.
Talia continued her undefeated streak, successfully defending her title against Alere Little Feather, Luscious Lily, Cindy Rogers, Officer Mercy, and against Feather and Alicia in a triple threat match.
In the summer of 2010, Sky began showing signs of a face turn, when Rayne began talking down to her and Von Erich, declaring that she did not need either of them, and then recruited a mystery woman hiding behind a motorcycle helmet to help her in her feud with Angelina Love.
The following week, Sky cemented her face turn by attacking the mystery woman during Rayne's title match with Angelina Love, and in doing so caused a distraction, which cost Rayne the Knockouts Championship. , Sky reunited with Angelina Love, accompanying her to the ring and helping her successfully defend the Knockouts Championship against Rayne.
On the February 24, 2005 episode of WWE Smack Down!
, she appeared as an extra during the JBL "Celebration of Excellence" party.
At the December Turning Point pay-per-view, Sky and Angelina Love formed an alliance and were dubbed Velvet Love Entertainment, Around this time, Sky and Love added another factor to their gimmicks, placing brown paper bags over their opponents heads after defeating them.